Doesn't that also happen if your starter battery and your Pb leisure batteries are also fully charged.?Indeed and just for clarity, I'm not having a dig, just trying to understand the thought process, this being a route I may well go when I can source the batteries I want.
In my case I have two alternators, a 24v one for the vehicle and a separate 12v one just for the leisure side. My concern would be that if I was in a sunny place my PV setup could have totally charged the battery bank, then I start the engine and ive straight away got 50+ additional amps going into them until the alternator realises they re full?