Yep I get the theory. My worry is the max charge current as my van has reasonably good and short cable runs:-(Depends, theoretically can max out the bms. How much flow? Depends on wire resistance path. If resistance path is low, current will flow until bms or alternator maxed out. If wire will limit based on output voltage, ( no regen braking), a lower current will make it to the battery. What you don’t have, is a charger to call it quits when full. The alternator does not know when it’s full, it will trickle if voltage is held high.
LiFePo4 can fully charge even at 13,6v, it’s just a longer process. The 14,4-14-6v it’s just spending up the bulk rate pushing more amps in a shorter time span.
Regarding the B2B recognising a full battery, surely the charge profile means they will go into absorption mode and will hold the battery at 14.2 for several hours anyway (Victron state 2 hrs for their B2B on lithium) ? So for most reasonable journeys it’s never going to do anything the alternator wouldn’t do on its own?