The voltage while charging should not be taken as an indication of how charged the battery is. Battery charging is a chemical process that takes several hours to complete. The voltage while charging typically rises immediately to about 13V, then gradually rises over several hours until it reaches about 14.4V. At that point it's still only about 80% charged.
During discharge, the plate materials in the battery (lead, lead oxide) change into lead sulfate, which is an amorphous gooey substance. During charging, the lead sulfate turns back into the plate materials again. This is the normal charge/discharge process.
If the lead sulfate is left for a long time (a week or two) it starts crystallising. The lead sulfate crystals can't be turned back into the plate materials by the normal charging process, so the battery loses capacity. This process is called sulphation.
So to avoid sulphation it's best to ensure the battery is fully 100% charged at least once a fortnight, preferably once a week.
During discharge, the plate materials in the battery (lead, lead oxide) change into lead sulfate, which is an amorphous gooey substance. During charging, the lead sulfate turns back into the plate materials again. This is the normal charge/discharge process.
If the lead sulfate is left for a long time (a week or two) it starts crystallising. The lead sulfate crystals can't be turned back into the plate materials by the normal charging process, so the battery loses capacity. This process is called sulphation.
So to avoid sulphation it's best to ensure the battery is fully 100% charged at least once a fortnight, preferably once a week.
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