As a matter of interest does the power flow to the starter battery show on the app screen....I have the 50a B2B with mppt works superbly except it only occasionally/very rarely shows the SB being charged...but I have a built in voltmeter on the dash and as soon as the lb if full the voltage of the SB rises but no charge is shown in the appI have an Ablemail which is a battery master type device, though can be configured to only transfer power if your preset volyage conditions of the two batteries are met.
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They don't all do this, but the Renogy 50A combined B2B and MPPT controller that I fitted will send spare solar generated power to the starter battery if the leisure battery is full. It uses the same connection for this that it uses to take power from the starter battery/alternator in B2B mode when the engine is running.